Difference between Austenitic and Martensitic Stainless Steel

 

What Is The Difference Between Austenitic And Martensitic Stainless Steel ?


By producing martensite, martensitic stainless steel is produced. Iron that has been cubically centred and crystallised becomes martensite. The majority of martensitic stainless steels are produced by rapidly cooling austenite after it has been heated. The action is referred to as quenching. The material's quick cooling stops cementite development. Additionally, the procedure stops extra carbon atoms from being expelled and instead artificially retains them inside the material.

The martensitic stainless steels benefit from extremely high abrasion resistance and toughness as a result. The microstructure, where trapped carbon provides great toughness, is in charge of abrasion resistance. Martensitic stainless steels have stronger strength, abrasion resistance, and toughness than their austenitic equivalents, but they exhibit less corrosion resistance. Applications requiring the management of heavy wear and tear, such as platforms, transportation, abrasive surfaces, etc., choose materials with these characteristics. A structure's ability to resist deformation under smaller stresses depends on the material's toughness.

Welding Austenitic And Martensitic Stainless Steel

Almost all metallic applications require welding of the steels. The type of material has an impact on the welding needs, welding speed, and welding ease. Compared to martensitic stainless steels, austenitic stainless steels are much simpler to weld. Compared to the majority of their austenitic counterparts, martensitic steels contain more carbon. As a result, the danger of chromium carbide precipitation during welding increases, toughness increases, and corrosion resistance decreases.

Martensitic steels must also be warmed to a specific temperature in order to be properly welded. Although post-weld heat treatments are not necessary for all austenitic stainless steels, they are necessary for martensitic stainless steels in order to harden them and prevent embrittlement. After welding, the martensitic steels' corrosion resistance will drop, whereas austenitic stainless steels continue to be corrosion-resistant.

The 304 austenitic stainless steel is the material type that is most frequently welded. Most austenitic stainless steels have lower carbon levels and chromium values ranging from 16 to 26 percent and up to 22 percent, respectively. This enables them to maintain their corrosion resistance and withstand the welding process. The martensitic grades contain a high carbon content and chromium contents ranging from 12 to 18 percent. To prevent welding cracking, welding must be conducted carefully to restricted joints and extremely thick pieces.

Austenitic And Martensitic Stainless Steel Grades

The 400 series of stainless steels contains martensitic steel grades. They range from 0.15 to 0.63 percent carbon by weight. The martensitic stainless steel comes in grades 410, 420, 440A, 420 ultra hone, and 410 Cb. The 200 and 300 series of materials contain austenitic stainless steels. Among the austenitic stainless steels are the nitronic 30, 201, 301, 304, 316, 309, and 316. The martensitic stainless steels are frequently used in cutlery, medical equipment, cookware, stampings for automobiles, staplers, springs, scissors, screwdrivers, industrial blades, pliers, etc. The austenitic stainless steels are utilised in virtually all home, commercial, and architectural settings, as well as in the oil and gas industries.

 

grades of Austenitic stainless steel
  • 304L
  • 304
  • 316
  • 303
  • 301
  • 316Ti
  • 316L
  • 321

 

Chemical Composition Standard Of Austenitic stainless steel
EURONORM (EN) STANDARD EN DESIGNATION AISI GRADE C CR MO NI OTHERS
1.4310 X10CrNi18-8 301 0.10 17.5 NS 8 NS
1.4301 X5CrNi18-10 304 < 0.07 18.5 NS 9 NS
1.4307 X2CrNi18-9 304L < 0.030 18.5 NS 9 NS
1.4305 X8CrNiS18-9 e 303 < 0.10 18 NS 9 0.3
1.4541 X6CrNiTi18-10 321 < 0.08 18 NS 10.5 Ti: 5×C ≤ 0.70
1.4401 X5CrNiMo17-12-2 316 < 0.07 17.5 2.2 11.5 NS
1.4404 X2CrNiMo17-12-2 316L < 0.030 17.5 2.25 11.5 NS
1.4571 X6CrNiMoTi17-12-2 316Ti < 0.08 17.5 2.25 12 Ti: 5×C ≤ 0.70

 

Various grades of Martensitic stainless steel
  • 431
  • 630 (17/4PH)
  • 430F
  • 410
  • 440C
  • 420

 

Chemical Structure Of Martensitic stainless steel
EN Steel designation European EN AISI C Cr Mo Others
X12Cr13 1.4006 410 0.12 12.5 - -
X20Cr13 1.4021 420 0.20 13.0 - -
X50CrMoV15 1.4116 - 0.50 14.5 0.65 V: 0.15
X14CrMoS17 1.4104 430F 0.14 16.5 0.40 S: 0.25
X39CrMo17-1 1.4122 - 0.40 16.5 1.10 -
X105CrMo17 1.4125 440C 1.10 17.0 0.60 -
X17CrNi16-2 1.4057 431 0.17 16.0 - Ni: 2.00
X4CrNiMo16-5-1 1.4418 - ≤ 0.06 16.0 1.10 Ni: 2.00
X5CrNiCuNb16-4 1.4542 630 (17/4PH) ≤ 0.07 16.0 - Ni: 4.00

Cu: 4.00

Nb: 5xC to 0.45

 

Minimum Yield Strength Chart Of Martensitic stainless steel
EN MININMUM YIELD STRESS, MPA TENSILE STRENGTH, MPA MINIMUM ELONGATION, % HEAT TREATMENT
1.4006 450 650 - 850 15 QT650
1.4021 600 650 - 850 12 QT800
1.4122 550 750 - 950 12 QT750
1.4057 700 900 - 1050 12 QT900
1.4418 700 840 - 1100 16 QT900
1.4542 790 960 - 1160 12 P960

 

Most Common types Austenitic stainless steel standard
  • European Standards (EN)
  • SAE (also AISI, USA)
  • British Standards/ UK (BS)
  • Japan Industrial Standards (JIS)
  • International Standards Organisation (ISO)
  • Germany Standard (DIN)
  • UNS (USA)
  • GB (China)

 

austenitic stainless steel 300 series
SERIES GRADE
300 Series 301 - 302 - 303 - 304/L - 304H - 316/L - 317L - 317LMN - 321 - 321H - 347 - 347H -309 - 309S - 310 - 310S - 310H - 330